Electrical and Electro-Thermal Characteristics of (Carbon Black-Graphite)/LLDPE Composites with PTC Effect.

Electrical properties and electro-thermal behavior were studied in composites with carbon black (CB) or hybrid filler (CB and graphite) and a matrix of linear low-density polyethylene (LLDPE). LLDPE, a (co)polymer with low crystallinity but with high structural regularity, was less studied for Positive Temperature Coefficient (PTC) applications, but it would be of interest due to its higher flexibility as compared to HDPE. Structural characterization by scanning electron microscopy (SEM) confirmed a segregated structure resulted from preparation by solid state powder mixing followed by hot molding. Direct current (DC) conductivity measurements resulted in a percolation threshold of around 8% (w) for CB/LLDPE composites. Increased filler concentrations resulted in increased alternating current (AC) conductivity, electrical permittivity and loss factor. Resistivity-temperature curves indicate the dependence of the temperature at which the maximum of resistivity is reached (Tmax(R)) on the filler concentration, as well as a differentiation in the Tmax(R) from the crystalline transition temperatures determined by DSC. These results suggest that crystallinity is not the only determining factor of the PTC mechanism in this case. This behavior is different from similar high-crystallinity composites, and suggests a specific interaction between the conductive filler and the polymeric matrix. A strong dependence of the PTC effect on filler concentration and an optimal concentration range between 14 and 19% were also found. Graphite has a beneficial effect not only on conductivity, but also on PTC behavior. Temperature vs. time experiments, revealed good temperature self-regulation properties and current and voltage limitation, and irrespective of the applied voltage and composite type, the equilibrium superficial temperature did not exceed 80 °C, while the equilibrium current traversing the sample dropped from 22 mA at 35 V to 5 mA at 150 V, proving the limitation capacities of these materials. The concentration effects revealed in this work could open new perspectives for the compositional control of both the self-limiting and interrupting properties for various low-temperature applications.

A sustainable bio-based char as emerging electrode material for energy storage applications.

In the last few years, extensive research efforts have been made to develop novel bio-char-based electrodes using different strategies starting from a variety of biomass precursors as well as applying different thermochemical conversion paths. In this regard, hydrothermal carbonization method is becoming a more prevalent option among conversion procedures even if pyrolysis remains crucial in converting biomass into carbonaceous materials. The main aim of this study is to develop an innovative supercapacitor electrode from spruce bark waste through a unique low-temperature technique approach, which proved to effectively eliminate the pyrolysis step. Consequently, a hybrid spruce-bark-graphene oxide compound (HySB) was obtained as electrode material for supercapacitors. When compared to a regularly used commercial electrode material, SLC1512P graphite (reference) with 150.3 µF cm-2 capacitance, the HySB has a substantially higher capacitive performance of 530.5 µF cm-2. In contrast to the reference, the HySB polarization resistance increases by two orders of magnitude at the stationary potential and by three orders of magnitude at the optimum potential, underlying that the superior performances of HySB extend beyond static conditions. The synthesis strategy provides an appropriate energy-efficient option for converting biomass into carbonaceous materials with meaningful properties suitable for energy storage applications.

Bioremediation of Wastewater Using Yeast Strains: An Assessment of Contaminant Removal Efficiency.

The main goal of wastewater treatment is to significantly reduce organic compounds, micronutrients (nitrogen and phosphorus) and heavy metals and other contaminants (pathogens, pharmaceuticals and industrial chemicals). In this work, the efficiency of removing different contaminants (COD, NO3-, NO2-, NH4+, PO43-, SO42-, Pb2+, Cd2+) from synthetic wastewater was tested using five different yeast strains: Kluyveromyces marxianus CMGBP16 (P1), Saccharomyces cerevisiae S228C (P2), Saccharomyces cerevisiae CM6B70 (P3), Saccharomyces cerevisiae CMGB234 (P4) and Pichia anomala CMGB88 (P5). The results showed a removal efficiency of up to 70% of COD, 97% of nitrate, 80% of nitrite, 93% of phosphate and 70% of sulfate ions for synthetic wastewater contaminated with Pb2+ (43 mg/L) and Cd2+ ions (39 mg/L). In contrast, the results showed an increase in ammonium ions, especially in the presence of Pb2+ ions. The yeast strains showed a high capacity to reduce Pb2+ (up to 96%) and Cd2+ (up to 40%) ions compared to the initial concentrations. In presence of a crude biosurfactant, the removal efficiency increased up to 99% for Pb2+ and 56% for Cd2+ simultaneously with an increase in yeast biomass of up to 11 times. The results, which were obtained in the absence of aeration and in neutral pH conditions, proved a high potential for practical applications in the biotreatment of the wastewater and the recovery of Pb and Cd ions, with a high benefit-cost ratio.

Metal and Metal Oxide Nanoparticle Incorporation in Polyurethane Foams: A Solution for Future Antimicrobial Materials?

With the technological developments witnessed in recent decades, nanotechnology and nanomaterials have found uses in several common applications and products we encounter daily. On the other hand, polyurethane (PU) foams represent an extremely versatile material, being widely recognized for their extensive application possibilities and possessing a multitude of fundamental attributes that enhance their broad usability across various application fields. By combining the versatility of PU with the antimicrobial properties of nanoparticles, this emerging field holds promise for addressing the urgent need for effective antimicrobial materials in various applications. In this comprehensive review, we explore the synthesis methods, properties and applications of these nanocomposite materials, shedding light on their potential role in safeguarding public health and environmental sustainability. The main focus is on PU foams containing metal and metal oxide nanoparticles, but a brief presentation of the progress documented in the last few years regarding other antimicrobial nanomaterials incorporated into such foams is also given within this review in order to obtain a larger image of the possibilities to develop improved PU foams.

Radiation Processing of Styrene-isoprene-styrene/Poly(ε-caprolactone) Blends.

The irradiation consequences on styrene-isoprene-styrene (SIS)/poly(ε-caprolactone) (PCL) blends are discussed starting from the oxidation initiation. Three characterization methods: chemiluminescence, differential scanning calorimetry and FTIR spectroscopy are applied. The differences that exist between the two components are revealed, when the oxidation rates of the inspected formulas depend on the blending proportion and the degradation conditions. The relevant activation energies characterizing the oxidation strength as well as the kinetic parameters of degradation during the accelerated damaging of blended polymers are related to the inhibition protection of PCL on the faster oxidation of SIS. The interaction between mixed components is revealed by the structural modifications simultaneously accompanied by the competition of formation and decay of radicals.

Nutrient and organic pollutants removal in synthetic wastewater by Pseudomonas aeruginosa and Chryseobacterium sp./biofilter systems.

Nutrient and organic pollution raise serious problems for aquatic ecosystems through the accumulation of organic carbon, the reduction of light penetration, and the loss of submerged aquatic vegetation. The over-enrichment of water with nitrogen and phosphorus leads to an imbalance in nutrient ratios, creating favorable conditions for toxic algal blooms, formation of oxygen-depleted water, etc. Thus, developing new technological solutions to reduce their amount is imperative. The present study investigates the capacity of Pseudomonas aeruginosa and Chryseobacterium sp. bacterial strains to form biofilm on solid support (biofilter), both individually and in tandem, using various analytical techniques. Also, the biofilm/biofilter systems' efficiency in removing nutrients such as nitrate, nitrite, ammonium, and phosphate ions from municipal wastewaters is assessed. The results showed a reduction of nutrient pollution of up to 91%, 98%, 55%, and 71% for nitrite, nitrate, ammonium, and phosphate ions. A reduction of about 78% of COD was also observed. The results were obtained in the absence of an additional aeration process, thus having a great potential for reducing total costs of wastewater treatment and developing ecological systems for wastewater management.

On the Use of Oxidation Induction Time as a Kinetic Parameter for Condition Monitoring and Lifetime Evaluation under Ionizing Radiation Environments.

The durability of polymeric materials is closely linked to their degradation under specific operating conditions when different stressors-general or specific, such as high temperature, sunlight or ionizing radiation, solvents, or mechanical stresses-act simultaneously, causing degradation. In the case of electrical cables, the durability of the electrically insulating materials used in their construction is an important parameter to ensure their operational security. In this work, we studied the degradation state of various types of electrical insulating materials from cables used in particle acceleration systems under European Organization for Nuclear Research (CERN) conditions (e.g., Super Proton Synchrotron, SPS) as a function of time and irradiation dose. A simple kinetic model was proposed based on the exponential decrease in the antioxidant amount in polymeric insulations. The onset oxidation time (OIT) values, used as an indicator of antioxidant concentration, were obtained from isothermal differential scanning calorimetry (DSC) and chemiluminescence (CL) measurements. Fourier transform infrared (FTIR) measurements were used to assess the degradation state and identify polymeric materials. The practical applicability of such a model in diagnosing degradation and in the subsequent evaluation of the remaining service life is of interest, as it can be adapted to a broad range of operating conditions and materials.

Polymer Composites with Self-Regulating Temperature Behavior: Properties and Characterization.

A novel conductive composite material with homogeneous binary polymer matrix of HDPE (HD) and LLDPE (LLD), mixed with conductive filler consisting of carbon black (CB) and graphite (Gr), was tested against a HDPE composite with a similar conductive filler. Even the concentration of the conductive filler was deliberately lower for (CB + Gr)/(LLD + HD), and the properties of this composite are comparable or better to those of (CB + Gr)/HD. The kinetic parameters of the ρ-T curves and from the DSC curves indicate that the resistivity peak is obtained when the polymer matrix is fully melted. When subjected to repeated thermal cycles, the composite (CB + Gr)/(LLD + HD) presented a better electrical behavior than composite CB + Gr)/HD, with an increase in resistivity (ρmax) values with the number of cycles, as well as less intense NTC (Negative Temperature Coefficient) effects, both for the crosslinked and thermoplastic samples. Radiation crosslinking led to increased ρmax values, as well as to inhibition of NTC effects in both cases, thus having a clear beneficial effect. Limitation effects of surface temperature and current intensity through the sample were observed at different voltages, enabling the use of these materials as self-regulating heating elements at various temperatures below the melting temperature. The procedure based on physical mixing of the components appears more efficient in imparting lower resistivity in solid state and high PTC (Positive Temperature Coefficient) effects to the composites. This effect is probably due to the concentration of the conductive particles at the surface of the polymer domains, which would facilitate the formation of the conductive paths. Further work is still necessary to optimize both the procedure of composite preparation and the properties of such materials.

High-Efficiency Biocidal Solution Based on Radiochemically Synthesized Cu-Au Alloy Nanoparticles.

The use of nanotechnologies in the applied biomedical sciences can offer a new way to treat infections and disinfect surfaces, materials, and products contaminated with various types of viruses, bacteria, and fungi. The Cu-Au nanoparticles (NPs) were obtained by an eco-friendly method that allowed the obtaining in a one-step process of size controlled, well dispersed, fully reduced, highly stable NPs at very mild conditions, using high energy ionizing radiations. The gamma irradiation was performed in an aqueous system of Cu2+/Au3+/Sodium Dodecyl Sulfate (SDS)/Ethylene Glycol. After irradiation, the change of color to ruby-red was the first indicator for the formation of NPs. Moreover, the UV-Vis spectra showed a maximum absorption peak between 524 and 540 nm, depending on the copper amount. The Cu-Au NPs presented nearly spherical shapes, sizes between 20 and 90 nm, and a zeta potential of about -44 mV indicating a good electrostatic stability. The biocidal properties performed according to various standards applied in the medical area, in dirty conditions, showed a 5 lg reduction for Staphylococcus aureus, Pseudomonas aeruginosa, and Enterococcus hirae, a 5 lg reduction for both enveloped and non-enveloped viruses such as Adenovirus type 5, Murine Norovirus, and human Coronavirus 229E, and a 4 lg reduction for Candida albicans, respectively. Thus, the radiochemically synthesized Cu-Au alloy NPs proved to have high biocide efficiency against the tested bacteria, fungi, and viruses (both encapsulated and non-encapsulated). Therefore, these nanoparticle solutions are suitable to be used as disinfectants in the decontamination of hospital surfaces or public areas characterized by high levels of microbiological contamination.